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    • Thermochimica Acta Journal

    Papers
    Snythesis, Characterization and Thermal Dissociation of Cobalt(ii) Complexes of the Photoproducts of Octacyanomolybdate(iv) and -Tungstate(iv) with Ethylenediamine
    SI Ali,K Majid
    Thermochimica Acta（1998）SCI 3区
    Photosubstituted mixed ligand complexes of Co(II) with irradiated solutions of Mo(CN)84− and W(CN)84− with ethylenediamine have been synthesized. The complexes have been isolated and characterized by their elemental analysis and IR spectroscopy. The assigned formulae are Co2[Mo(C...
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    Structure and Reactivity of Solids
    ZG SZABO
    Thermochimica Acta（1988）SCI 3区
    The structural characteristics which determine the behaviour of solids under various conditions, especially during the interactions with other substances, are summarized.
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    Calorimetric Study of Binary Mixtures Containing Chlorobenzene + Linear and Cyclic Ethers
    F COMELLI,R FRANCESCONI
    Thermochimica Acta（1992）SCI 3区
    Excess molar enthalpies H E of binary mixtures containing chlorobenzene + five ethers (oxolane, oxane, 1,4-dioxane, dimethoxymethane and 1,2-dimethoxyethane) were determined at atmospheric pressure and at 298.15 K by means of a flow microcalorimeter. Experimental H E values were ...
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    Aspects of Polyesterurethane Interaction with Metallic Ions - Ii. Synthesis and Thermal Behavior of Polyurethane Interaction Products with Manganese and Copper Ions
    G Moroi,C Ciobanu
    Thermochimica Acta（2002）SCI 3区
    The objective of this study was to investigate the effects of some transition metal ions on the thermal behavior of polyurethane materials. The interaction products of a segmented polyesterurethane prepared from 4,4′-diphenylmethane diisocyanate, poly(ethylene-co-diethylene adipa...
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    Crystallization Kinetics and Morphology Studies of Biodegradable Poly(Butylene Succinate-Co-Butylene Adipate)/Multi-Walled Carbon Nanotubes Nanocomposites
    Siyu Zhu,Yuanyuan Zhao,Zhaobin Qiu
    Thermochimica Acta（2009）SCI 3区
    Biodegradable poly(butylene succinate-co-butylene adipate) (PBSA)/carboxyl-functionalized multi-walled carbon nanotubes (f-MWNTs) nanocomposites were prepared through solution casting method with different f-MWNTs contents ranging from 0.5 to 2 wt%. Scanning electron microscopic ...
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    The Glass Transition of Polymer Crystals
    Bernhard Wunderlich
    Thermochimica Acta（2006）SCI 3区
    The statement: “A solid is a condensed phase at a temperature below its glass transition”, is an operational definition. It leads to the corollary that for crystals to be solid, they must be below their glass transition. In this paper evidence for the usefulness of this definitio...
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    Binary and Ternary Compounds, Phase-Diagrams and Contaminations in the Yo1.5-Bao-Cuo System Auxiliary to Superconducting Ceramics
    J SESTAK
    Thermochimica Acta（1989）SCI 3区
    The binary phases and compatibilities of the BaO-CuO, YO1.5-BaO and YO1.5-CuO systems are discussed. The different variants of YBa2Cu3O7-y, are shown in dependence on y. So far reported existence of the ternary compounds (in the ratio Y:Ba:Cu) 1:3:2,1:4:3,1: :2:4,1:5:3,3:8:5,2:3:...
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    Diffusion Controlled Thermal Desorption
    DL MILLER,RH WILDNAUER
    Thermochimica Acta（1976）SCI 3区
    A special case of the non-isothermal rate equation is derived for the evaluation of thermal gravimetry data when the measured weight loss from a sheet-like specimen is governed by a diffusion process as opposed to a homogenous chemical reaction. The equation is applied to the des...
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    Determination of the Surface States of Metallic Clusters Supported on Alumina Using Microcalorimetry of Co Adsorption
    A Maroto-Valiente,I Rodriguez-Ramos,A Guerrero-Ruiz
    Thermochimica Acta（2001）SCI 3区
    The adsorption of CO on alumina supported metal (Rh, Ru, Pt and Pd) catalysts was studied by microcalorimetry and infrared spectroscopy. The correlation of the results obtained from these two techniques provides information about the CO adsorbed species and the variations in the ...
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    Thermodynamic Behaviour of Bulk Metallic Glasses
    P. K. Singh,K. S. Dubey
    Thermochimica Acta（2009）SCI 3区
    The thermodynamic behaviour of bulk metallic glass (BMG) forming melts have been studied by analyzing the temperature dependence of the Gibbs free energy difference (∆G), entropy difference (∆S) and enthalpy difference (∆H)between the undercooled melt and the corresponding equili...
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    Vaporization Chemistry and Thermodynamics in the Cdga2s4-Ga2s3 System
    JG EDWARDS,ST KSHIRSAGAR
    Thermochimica Acta（1982）SCI 3区
    The chemistry and thermodynamics of vaporization of CdGa2S4(s), CdGa8S13(s), and Ga2S3(s) were studied by computer-automated, simultaneous Knudsen-effusion and torsion-effusion, vapor pressure measurements in the temperature range 967–1280 K. The vaporization was incongruent with...
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    Density of Molten Sulfur in the 334-508 K Range
    Philippe Espeau,Rene Ceolin
    Thermochimica Acta（2007）SCI 3区
    As the density of elemental sulfur was determined on slowly cooling from 508K, it was unexpected for the metastable molten state to be maintained to temperatures as low as 334K, thus expanding by about 20K the T-range within which experimental data become available. In the 334–43...
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    Thermal Characterization of Some Polymorph Solvates of the Anti-Inflammatory/anti-cancer Sulindac
    Cristina Cavallari,Fabrizio Tarterini,Adamo Fini
    Thermochimica Acta（2016）SCI 3区
    Solvates of sulindac were obtained by crystallization from acetone, chloroform, dichloromethane and tetrahydrofuran, but not from water, methanol, ethanol and propanols, acetonitrile and ethyl acetate and were studied by thermal (differential scanning calorimetry DSC, thermogravi...
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    Estimation and Revision of Some Thermodynamic Data in the YBaCuO System. Part 1. Values of H⊖298 — H⊖0 and Temperatures of the Phase Transformations
    G MOISEEV,N VATOLIN,J SESTAK
    Thermochimica Acta（1994）SCI 3区
    Analysing literature data for the YBaCuO system, the values of H⊖298—H⊖0, and the temperatures of melting and decomposition were estimated and empirical equations for their calculation are discussed. The values of these characteristic data for YBa2Cu3O7 (123-O7), YBa2Cu3O6 (123-O...
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    The Use of Isothermal Calorimetry to Measure Corrosion Rates of Metals in Contact with Preservative-Treated Wood
    Samuel L. Zelinka,Samuel Glass, Eleanor Q. D. Lazarcik
    Thermochimica Acta（2023）SCI 3区
    The purpose of this paper is to examine whether isothermal microcalorimetry can be used to determine the corrosion rates of metals embedded in wood. Metal fasteners were driven into dowels of wood treated with alkaline copper quaternary, a common wood preservative that increases ...
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    High-temperature Synthesis of Calcium Sulphoaluminate from Phosphogypsum
    G VALENTI,L SANTORO,R GAROFANO
    Thermochimica Acta（1987）SCI 3区
    The possibility of using phosphogypsum for the production of cements based on calcium sulphoaluminate (3CaO·3Al2O3·CaSO4), which is of interest in the fields of rapid-hardening, expansive and energy-saving hydraulic binders, has been examined.
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    Retirement of Prof. H. Kambe
    Jaroslav Šesták
    Thermochimica Acta（1981）SCI 3区
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    A Thermal Decomposition Study on Cobalt(ii) Complexes of 1,2-Bis(imino-4'-antipyrinyl)ethane
    N. T. Madhu,P. K. Radhakrishnan,M. Grunert,P. Weinberger,W. Linert
    Thermochimica Acta（2004）SCI 3区
    The phenomenological, kinetic and mechanistic aspects of thermal decomposition of perchlorate, nitrate, chloride, bromide and iodide complexes of cobalt(II) with the Schiff base 1,2-bis(imino-4'-antipyrinyl)ethane (GA) have been studied by TG and DTG analyses. The kinetic paramet...
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    Miscibility of Poly(vinyl Chloride) with Terpoly(α-Methylstyrene-acrylonitrile-methyl Methacrylate)
    T KOVACIC,B BARIC,I KLARIC
    Thermochimica Acta（1994）SCI 3区
    The miscibility of poly(vinyl chloride)/terpoly(α-methylstyrene-acrylonitrile-methyl methacrylate) (PVC/MS-AN-MMA) blend was investigated by differential scanning calorimetry. The parameters of thermal transitions and phase behaviour of the blend were determined. Using the criter...
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    Specific-Heats And Kinetic-Parameters Of Thermooxidative Decomposition Of Peanut Oil
    T. Kasprzycka-Guttman,M. Jarosz-Jarszewska,G. Litwinienko
    Thermochimica Acta（1995）SCI 3区
    The kinetics of thermo-oxidative decomposition of peanut oil have been investigated using a Du Pont differential scanning calorimeter. The measurements were carried out under dynamic conditions in an atmosphere of oxygen. The activation energy of oxidation of the oil is calculate...
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