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Cover Feature: Exploring Lithium Storage Mechanism and Cycling Stability of Bi2Mo3O12 Binary Metal Oxide Anode Composited with Ti3C2 MXene (batteries & Supercaps 12/2020)

Batteries &amp Supercaps(2020)

Soochow University (Suzhou) | Materials Science Group

Cited 0|Views6
Abstract
The Cover Feature illustrates the lithium storage mechanism of binary metal oxide Bi2Mo3O12 as high-capacity anode material. The “parent” Bi2Mo3O12 undergoes a typical conversion reaction into metallic Bi and Li2MoO4 components (represented by the children) during initial lithiation process, followed by reversible lithium storage through alloying/de-alloying of Li3Bi and intercalating/de-intercalating of Li2+xMoO4 for eventual capacity contribution. Compositing Bi2Mo3O12 with Ti3C2-based MXene significantly improves cycle stability and rate capability of the Bi2Mo3O12/Ti3C2 anode material. More information can be found in the Article by Yan-Gu Lin, Jianqing Zhao, Lijun Gao and co-workers.
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要点】:研究二元金属氧化物Bi2Mo3O12作为高容量负极材料的锂存储机制,并探究其与Ti3C2 MXene复合后循环稳定性和倍率性能的提升。

方法】:通过分析Bi2Mo3O12在初始锂化过程中的典型转换反应,以及与Li3Bi合金化/去合金化和Li2+xMoO4的插层/去插层反应的循环锂存储机制,结合复合Ti3C2 MXene来改善性能。

实验】:采用Bi2Mo3O12/Ti3C2复合材料进行电化学测试,实验结果证实了该复合材料的循环稳定性和倍率性能显著提高,具体数据集名称未在摘要中提供。