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    • Macromolecular Chemistry and Physics Journal

    Papers
    Association Behavior of Linear Ω‐functionalized Polystyrenes in Dilute Solutions
    A BORLENGHI,M PITSIKALIS,S PISPAS,N HADJICHRISTIDIS
    Macromolecular Chemistry And Physics（1995）SCI 4区
    Linear polystyrenes with dimethylamino end groups were prepared by anionic polymerization, using 3-(dimethylamino)propyllithium as initiator and high vacuum techniques. The amino group was transformed to a sulfozwitterionic moiety by reaction with 1,3-propanesultone. The dilute s...
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    Highly Active Single-Site Catalysts For The 1,4-Cis Polymerization Of Butadiene From Allylneodymium(Iii) Chlorides And Trialkylaluminiums - A Contribution To The Activation Of Tris(Allyl)Neodymium(Iii) And The Further Elucidation Of The Structure-Activity Relationship
    S Maiwald,C Sommer,G Muller,R Taube
    Macromolecular Chemistry And Physics（2002）SCI 4区
    Full Paper To further elucidate the structure-reactivity relationship in the allyneodymium complex-catalyzed 1,4-cis polymerization of butadiene, the following catalyst systems are investigated in toulene more thoroughly: Nd(C3H5)(2)Cl.4,4-dioxane, Nd(C3H5)Cl-2.2.5 tetrahydrofura...
    Cited53Views4
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    Untersuchungen Über Die Γ‐struktur in Unverstrecktem Und Verstrecktem 6‐Polyamid
    K. H. Illers,H. Haberkorn,P. Simák
    Macromolecular Chemistry And Physics（1972）SCI 4区
    AbstractDie in der monoklinen α‐Struktur kristallisierten Bereiche des unverstreckten und verstreckten 6‐Polyamids wandeln sich bei der Behandlung mit wäßriger Jod‐Alkalijodid‐Lösung in die γ‐Struktur um. Diese γ‐Struktur wird röntgenographisch, IR‐spektroskopisch und kalorimetri...
    Cited85Views4
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    Synthese Von Verbindungen Der Cellulose Mit Eiweißstoffen
    F MICHEEL,J EWERS
    Macromolecular Chemistry And Physics（1949）SCI 4区
    AbstractOxy‐cellulose wird nach der Azid‐methode an Eiweißstoffe gebunden. In ihrer Kettenlänge nicht abgebaute Cellulose wird über ihre Glykolsäure‐äther nach der Azid‐methode mit Proteinen kondensiert. Es werden zwei Typen von Stoffen erhalten. Bei den kohlenhydratarmen ist jed...
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    Controlled and Living Polymerizations: from Mechanisms to Applications
    Patrick Theato
    Macromolecular Chemistry And Physics（2010）SCI 4区
    Macromolecular Chemistry and PhysicsVolume 211, Issue 7 p. 833-834 Book Review Controlled and Living Polymerizations: From Mechanisms to Applications Patrick Theato, Patrick Theato Mainz (Germany) Seoul (Korea)Search for more papers by this author Patrick Theato, Patrick Theato M...
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    Comparative Study on Activation Rate Constants for Some Styrene/Nitroxide Systems
    A Goto, T Fukuda
    Macromolecular Chemistry And Physics（2000）SCI 4区
    The activation rate constants k(act) of some polystyrene (PS) - nitroxide adducts were determined as a function of temperature by the GPC peak resolution method. The results showed that both the steric and polar factors associated with the structure of the nitroxides strongly aff...
    Cited56Views1
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    Nematic Elastomers: the Dependence of Phase Transformation and Orientation Processes on Crosslinking Topology
    A Greve,H Finkelmann
    Macromolecular Chemistry And Physics（2001）SCI 4区
    The orientation process in response to a mechanical field and the phase transformation of nematic elastomers are investigated for different types of crosslinkers and their concentration. For the corresponding linear polymer melt a mechanical field causes a director orientation pe...
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    Molecular Changes in Vapor‐Based Polymer Thin Films Assessed by Characterization of Swelling Properties of Amine‐Functionalized Poly‐p‐xylylene
    Meike Koenig,Vanessa Trouillet,Alexander Welle,Karsten Hinrichs,Joerg Lahann
    Macromolecular Chemistry And Physics（2020）SCI 4区
    Though widely applied in various technological areas, the knowledge about the molecular behavior of poly-p-xylylene and its derivatives prepared via chemical vapor deposition polymerization is still far from comprehensive, as for this polymer the characterization is limited due t...
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    Soluble and Film-Forming Cellulose Derivatives with Redox-Chromogenic and Enzyme Immobilizing 1,4-Phenylenediamine Groups
    J Tiller,P Berlin,D Klemm
    Macromolecular Chemistry And Physics（1999）SCI 4区
    Cellulose architectures with redox-chromogenic properties and anchor groups for the immobilization of biomolecules have been prepared by reaction of p-toluenesulfonic acid esters of cellulose (tosylcellulose, DS 2.3) with 1,4-phenylenediamine (PDA) in dimethyl sulfoxide (DMSO) so...
    Cited48Views2
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    Hyperbranched Fluoropolymers and Their Hybridization into Complex Amphiphilic Crosslinked Copolymer Networks
    Jeremy W. Bartels,Chong Cheng,Kenya T. Powell,Jinqi Xu,Karen L. Wooley
    Macromolecular Chemistry And Physics（2007）SCI 4区
    This feature article highlights three types of hyperbranched fluoropolymers (HBFPs) with different structural features, which were synthesized by either polycondensation of fluorinated AB(chi) monomers or self-condensing vinyl (co)polymerization of fluorinated inimers and/or fluo...
    Cited60Views2
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    Zur Problematik Der Ermittlung Von Viskositätszahlen Aus Strukturviskosen Lösungen. (viskositätsmessungen an Nativen Dextranen)
    F PATAT, J HARTMANN
    Macromolecular Chemistry And Physics（1956）SCI 4区
    AbstractLösungen sehr hochmolekularer Dextrane zeigen noch im Bereich kleiner Konzentrationen so starke Abweichungen vom Newton schen Verhalten, daß die Ermittlung schubspannungsunabhängiger Viskositätszahlen auf dem üblichen Wege nicht mehr gelingt. Das Fließverhalten solcher De...
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    Kinetics and Mechanism for the Reaction Between Electrochemically Produced Naphthalene Radical‐anions and Ethylene and Propylene Oxides
    G MENGOLI,G VIDOTTO, FURLANET.F
    Macromolecular Chemistry And Physics（1970）SCI 4区
    AbstractThe reaction between naphthalene radical‐anions produced through electrochemical reduction of naphthalene and ethylene and propylene oxides has been investigated in dimethylformamide at various temperatures using amperometric and polarographic techniques. The decay rate o...
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    Intramolecular Screening and Functional Group Accessibility Effects in Polymer Blends: the Prediction of Phase Behavior
    MM Coleman,PC Painter
    Macromolecular Chemistry And Physics（1998）SCI 4区
    Using modified equations for the free energy of mixing of hydrogen bonded polymer blends that include the effects of intramolecular screening and functional group accessibility, we have been able to predict and duplicate experimentally observed miscibility maps for ethylene-stat-...
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    Spezifische Wärmen Und Einfrierwärmen Eines Polystyrols Mit Verschiedener Temperaturbehandlung
    H MARTIN, FH MULLER
    Macromolecular Chemistry And Physics（1964）SCI 4区
    AbstractDynamische Messungen der spezifischen Wärme am Polystyrol zeigen, daß die Ergebmisse von der vorangehenden Temperatur‐Zeit‐Behandlung abhängen. Bei Variation der Abkühlgeschwindigkeit treten in den nachfolgenden Aufheizmessungen zwischen 50 und 100°C Unterschiede im cp‐Ve...
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    Kinetic Studies of the Anionic Polymerization of Methyl Methacrylate in Tetrahydrofuran with Na+ As Counter Ion, Using Monofunctional Initiators
    V WARZELHAN,H HOCKER,GV SCHULZ
    Macromolecular Chemistry And Physics（1978）SCI 4区
    AbstractA newly designed automatically controlled stirred reactor suitable for kinetic measurements of reactions with half lives ≥2s has been applied to follow the anionic polymerization of methyl methacrylate in THF with Na+ as a counter ion in the presence of an excess of NaB(C...
    Cited49Views7
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    Blend of Poly(ɛ-caprolactone) and 4,4′-Thiodiphenol: Hydrogen Bond Formation and Some Solid Properties
    Y He,N Asakawa,Y Inoue
    Macromolecular Chemistry And Physics（2001）SCI 4区
    The formation of the inter-associated hydrogen bond between poly(ε-caprolactone) (PCL) and 4,4′-thiodiphenol (TDP) was investigated as a function of composition and temperature by temperature-variable Fourier transform infrared spectroscopy. It was found that the fractions of ass...
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    Condensation Polymerization of N‐dithiocarbonyl Alkoxyearbonyl Amino Acids. Part V. Studies on Reaction Mechanism
    H KATO,HIGASHIM.T,S OKAMURA
    Macromolecular Chemistry And Physics（1967）SCI 4区
    AbstractN‐Dithiocarbonyl ethoxycarbonyl amino acids (DTE‐amino acids) (I) are easily converted to high molecular polypeptides by heating in dioxane. To elucidate the reaction mechanism, the formation of by‐products or intermediates in the polymerization of DTE‐glycine and ‐alanin...
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    Substituierte Silylderivate Des Pektins Und Der Glucose
    FA HENGLEIN,K SCHEINOST
    Macromolecular Chemistry And Physics（1956）SCI 4区
    AbstractDurch Einwirkung von Siliziumtetrachlorid sowie Alkyl‐ und Arylchlorsilanen auf Pektin in Gegenwart von HCl‐bindenden Verbindungen (Pyridin und Formamid) wurden Kieselsäureester und substituierte Silylderivate des Pektins erhalten. In gleicher Weise wurde eine Penta‐(trim...
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    Self-Assembly and Viscoelastic Properties of Semifluorinated Polyesters
    A Gottwald,D Pospiech,D Jehnichen,L Haussler,P Friedel,J Pionteck,M Stamm,G Floudas
    Macromolecular Chemistry And Physics（2002）SCI 4区
    The structure and dynamics of polyesters composed from a rigid aromatic backbone and oxyalkyl-perfluoroalkyl side chains have been studied using differential scanning calorimetry, small- and wide-angle X-ray scattering, pressure-volume-temperature measurements and rheology. The s...
    Cited34Views13
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