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Synthesis, Structure and Magnetism of RTa7O19 (R = Pr, Sm, Eu, Gd, Dy, Ho) with Perfect Triangular Lattice

Journal of Alloys and Compounds(2023)SCI 2区

Wuhan National High Magnetic Field Center & School of Physics | Huazhong Univ Sci & Technol

Cited 3|Views10
Abstract
We present the synthesis, structure and magnetic properties of a hitherto unstudied family of rare-earth based RTa7O19 (R = Pr, Sm, Eu, Gd, Dy, Ho) compounds with space groupP6¯2c. The structural analysis reveals that magnetic R ions form layers of ideal two-dimensional triangular lattices in the ab-plane separated by several nonmagnetic polyhedra layers along the c-axis. The magnetic susceptibility and magnetization measurements indicate the absence of long-range magnetic order and field-induced magnetic transitions in all the studied compounds. The details about the magnetism strongly depend on the type of R ions. The presence of geometrical frustration is discussed. Thus, RTa7O19 provides a new platform for exploring the frustrated magnetism.
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Key words
Rare earth tantalates,Triangular lattice,Geometric magnetic frustration
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要点】:本研究首次报道了RTa7O19 (R = Pr, Sm, Eu, Gd, Dy, Ho)化合物的合成、结构和磁性质,揭示了其在几何受阻磁学领域的研究价值。

方法】:通过结构分析和磁化率测量,研究了这些化合物的磁性质。

实验】:在P6¯2c空间群中合成了RTa7O19系列化合物,并通过磁化率及磁化测量,发现所有研究化合物均无长程磁有序和场致磁相变,磁性质与R离子种类密切相关,表明存在几何受阻现象。数据集为合成的RTa7O19系列化合物的磁学测量结果。